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51.
Proton affinities of a series of triphenyl Group Va compounds have been determined by bracketing using reactant ion monitoring: (C6H5)3N = 904 ± 8 kJ mol?1, (C6H5)3P = 968 ± 5 kJ mol?1, (C6H5)3As = 904 ± 8 kJ mol?1 and (C6H5)3Sb = 846 ± 8 kJ mol?1. The large difference in substituent effect of phenyl for hydrogen between As or P and N may result from overlap of the 2p orbitals of N with the sp2 orbitals on the ring carbons and lack of overlap for P or As. Proton affinities of phenylalkylphosphine oxides are essentially the same, 904 ± 8 kJ mol?1, independent of alkyl group. 相似文献
52.
Nguyen Van Do Tran Duc Thiep Truong Thi An Tran Minh Duc Han Ngoc Cuong 《Journal of Radioanalytical and Nuclear Chemistry》1986,107(1):29-37
Photon activation analysis has been success-fully applied to the fast and non-destructive analysis of tin in cassiterite ores
based on the 159.7 keV gamma line of123mSn produced in the124Sn/γ, n/123mSn reaction. In order to improve the accuracy of analytical results, corrections for self-absorption and pile-up effects were
performed. Under typical conditions /15 μA electron beam current, 15 MeV bremsstrahlung energy, 5 min irradiation time and
10 min measurement/ the sensitivity of the analysis is 10 ppm. The proposed method can be used for routine analysis of tin
in geological samples. 相似文献
53.
Viñas P Aguinaga N López-García I Hernandez-Córdoba M 《Journal of AOAC International》2002,85(3):736-743
Procedures were developed for determining cadmium, aluminium, and copper in beer and the products used in its manufacture by electrothermal atomic absorption spectrometry. Beer samples were injected into the furnace and solid samples were introduced as suspensions after preparation in a medium containing hydrogen peroxide, nitric acid, and ammonium dihydrogen phosphate for cadmium atomization. Calibration was performed with aqueous standards, and characteristic masses and detection limits were, respectively, 1 and 0.3 pg for cadmium, 18 and 5.4 pg for aluminium, and 5.6 and 6.8 pg for copper. Different samples of beer, wort, brewer's yeast, malt, raw grain, and hops were analyzed by the proposed procedures. Cadmium was found in low concentrations (0.001-0.08 microg/g and 0-1.3 ng/mL); copper (3-13 microg/g and 25-137 ng/mL) and aluminium (0.6-9 microg/g and 0.1-2 microg/mL) were found at higher levels. The reliability of the procedure was confirmed by comparing the results obtained with others based on microwave oven sample digestion, and by analyzing several certified reference materials. 相似文献
54.
I. López-García E. Navarro P. Viñas M. Hernández-Córdoba 《Analytical and bioanalytical chemistry》1997,357(6):642-646
A method is proposed for the determination of Pb, Cd and Tl in cements by ETAAS. The samples are suspended in a medium containing
10% v/v ethanol and 1% v/v both conc. nitric and hydrofluoric acids and are directly introduced into the electrothermal atomizer.
The drying stage is performed by programming a 400 °C temperature, a ramp time of 5 s and a hold time of 30 s on the power
supply to the atomizer. No ashing step is used. Atomization is carried out at 2100, 1800 and 1700 °C for Pb, Cd and Tl, respectively.
For Cd determination, ammonium dihydrogen phosphate is added to the suspension medium. No modifier other than hydrofluoric
acid is required for the Pb and Tl determination. It is shown that the results obtained by using direct calibration with aqueous
standards for five commercial samples agree with those found by means of the standard additions method.
Received: 29 March 1996/Revised: 24 May 1996/Accepted: 30 May 1996 相似文献
55.
N,N-Diethyldithiocarbamate functionnalized 1,4-polyisoprenes were prepared from 1,4-polyisoprenes (natural or synthetic). The syntheses were performed by nucleophilic addition of N,N-diethyldithiocarbamate salts upon oxirane rings of epoxidized units according to a SN2 mechanism with ring opening. Studies on model molecules of epoxidized 1,4-polyisoprene units (1,2-epoxy-1-methylcyclohexane and 4,5-epoxy-4-methyloctane) were previously achieved to develop the procedure. The best yields were obtained at low temperature in polar medium, and more especially in water with sodium N,N-diethyldithiocarbamate (DEDT-Na) as reagent. A diastereospecific addition was noted when reaction was performed in water with DEDT-Na. Afterwards, the developed procedure was successfully generalized to epoxidized synthetic polyisoprenes and epoxidized natural rubber (in THF, then in latex medium). Excellent results were obtained in latex medium with epoxidized natural rubber (ENR) latices. As with the models, a diastereospecific addition of sodium N,N-diethyldithiocarbamate trihydrate onto epoxidized 1,4-polyisoprene units of ENR was observed at the condition to bring the latex medium to pH 8 before introduction of DEDT-Na. Influence of temperature, drc, and DEDT-Na concentration were successively examined to determine the best conditions of the addition on ENR latices. 相似文献
56.
Summary An ,-appended eighteen carbon chains hypercin derivative (2) was synthesized starting from emodin. The overall yield of the seven step synthesis was 12%. The1H and13C NMR, absorption, and emission spectroscopic properties were measured;2 can be dissolved even in apolar solvents and polyethylene.
Synthese und Eigenschaften eines mit C18-Ketten ,-substituierten Hypericinderivats
Zusammenfassung Ein in den Positionen , mit zwei C18-Ketten substituiertes Derivat des Hypericins (2) wurde ausgehend von Emodin synthetisiert. Die Gesamtausbeute der siebenstufigen Synthese betrug 12%. Die1H- und13C-NMR, absorptions- und emissionsspektroskopischen Eigenschaften wurden gemessen;2 kann sogar in apolaren Lösungsmitteln und Polyethylen gelöst werden.相似文献
57.
I. M. Skvortsov I. V. Antipova Yu. A. Pentin Tran Suan Khoan' S. V. Vasil'kovskii 《Chemistry of Heterocyclic Compounds》1975,11(8):949-955
1-(2-Furyl)-3-amino-4,4-dimethylpentane was used to obtain 3-tert-butyl-1,2-dihydropyrrolizine, the catalytic hydrogenation of which over Rh/Al2O3 at room temperature gives a mixture of cis- and trans-3,8-H-3-ter-butylpyrrolizidines with predominance of the cis isomer, whereas hydrogenation at 90–100 °C gives a mixture containing the trans isomer as the principal component. The three-dimensional structures of the isomers follow from data on the catalytic hydrogenation and isomerization and the IR, Raman, and PME spectra. A considerable percentage of the trans-fused form is characteristic for cis-3,8-H-3-tert-butylpyrrolizidine. 相似文献
58.
The self-diffusion coefficient, D, of dibutyltin dilaurate and dibutyltin bismonobutylmaleate have been obtained at 35, 45 and 55° in samples of poly(vinyl chloride) plasticized with 34, 60 and 100 phr of di(2-ethylhexyl)phthalate. D at 2 phr of the laurate is 3–5 times larger than for the smaller maleate molecule. In all cases, D increases with increasing plasticizer concentration, an effect interpreted in terms of the free volume theory of diffusion. D for the laurate increases by a factor of about 2.7 when the laurate diffusant concentration is increased from 0 to 4 phr. The activation energies for diffusion, ED, lie between 50 and 90 kJ mol?1. They increase with increasing plasticizer concentration but become constant at higher plasticizer concentrations (60–100 phr). It is impossible to correlate all the known data on diffusion in plasticized PVC with an equation of the form log D0 = C1 + C2 ED/RT 相似文献
59.
A set S of permutations of k objects is -uniform, t-homogeneous if for every pair A, B of t-subsets of the ground set, there are exactly permutations in S mapping A onto B. Arithmetical conditions and symmetries are discussed. We describe the character-theoretic method which is useful if S is contained in a permutation group. A main result is the construction of a 2-uniform, 2-homogeneous set of permutations on 6 objects and of a 3-uniform, 3-homogeneous set of permutations on 9 objects. These are contained in the simple permutation groups PSL
2(5) and PSL
2(8), respectively. The result is useful in the framework of theoretical secrecy and authentication (see Stinson 1990, Bierbrauer and Tran 1991). 相似文献